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Shimoyama, Iwao; Baba, Yuji; Hirao, Norie*
Advances in Engineering (Internet), 1 Pages, 2018/02
The performance of organic devices largely depends on molecular orientation in organic films. Whereas micro-orientation control of organic molecules is an indispensable technology for integration of organic devices, the method has not been established. We attempted to control micro-orientation of polydimethylsilane (PDMS) thin films by deposition of PDMS on graphite substrates modified by hetero atom doping using ion beam. Polarization dependence measurements of X-ray absorption spectroscopy and molecular orbital calculations clarified that PDMS films have lying, standing, and random orientations on the non irradiated, N-irradiated, and Ar-irradiated graphite surfaces, respectively. Furthermore, photoemission microscopy observation clarified that a PDMS film showed micro-patterns on a graphite surface with a microstructure on the order of m by separating N-irradiated and non irradiated areas. These results demonstrate our method is promising for micro-orientation of organic molecules.
Shimoyama, Iwao; Baba, Yuji; Hirao, Norie*
Applied Surface Science, 405, p.255 - 266, 2017/05
Times Cited Count:1 Percentile:5.94(Chemistry, Physical)NEXAFS spectroscopy is applied to study orientation structures of polydimethylsilane (PDMS) films deposited on heteroatom-doped graphite substrates prepared by ion beam doping. The Si -edge NEXAFS spectra of PDMS show opposite trends of polarization dependence for non irradiated and N-irradiated substrates, and show no polarization dependence for an Ar-irradiated substrate. Based on a theoretical interpretation of the NEXAFS spectra via first-principles calculations, we clarify that PDMS films have lying, standing, and random orientations on the non irradiated, N-irradiated, and Ar-irradiated substrates, respectively. Furthermore, photoemission electron microscopy indicates that the orientation of a PDMS film can be controlled with microstructures on the order of m by separating irradiated and non irradiated areas on the graphite surface. These results suggest that surface modification of graphite using ion beam doping is useful for micro-orientation control of organic thin films.
Ikeura, Hiromi*; Sekiguchi, Tetsuhiro
Photon Factory Activity Report 2013, Part B, P. 518, 2014/00
Organic electrically conducting -stacked small molecules are widely regarded as promising materials for future application of low-cost and flexible nanoelectronics. Pentacene is one of the most promising organic semiconductors because of its excellent device performance. Direct measurements of electronic structures of unoccupied states of organic semiconductors lead to better understanding of mechanism of electron conduction. For probing unoccupied partial density of states (DOS), X-ray absorption spectroscopy (XAS) is commonly used, where selective excitation of the 1s core electron to the unoccupied conduction band is possible. The molecular orientation of pentacene derivative has been investigated by angle dependent XAS measurements. Electronic states were calculated by DVX method.
Fujii, Kentaro
Hoshako, 16(3), p.151 - 158, 2003/05
no abstracts in English
Suzuki, Satoru; Sato, Haruo; Ishidera, Takamitsu; Fujii, Naoki*; Kawamura, Katsuyuki*
JNC TN8400 2001-031, 44 Pages, 2002/05
In order to quantify effect of temperature on diffusivity of deuterated water (HDO) in compacted sodium-bentonite, through-diffusion experiments were conducted at elevated tempemture from 298 to 333 K. Kunipia F (Na-montmorillonite content 98 wt. %; Kunimine Industly Co.) was compacted to a dry density of 0.9 and l.35 Mg/m. Since smectite flakes were perpendicularly oriented to a direction of compaction, anisotropy of diffusivity was investigated parallel and normal to the preferred orientation of smectite. Effective diffusion coeficient D of HDO was larger for a diffusional direction parallel to the preferred orientation than normal to that for both dry densities. These results well agreed to the previously reported ones for tritiated water. Activation energies of D in compacted bentonite increased with increasing dry density in the range of 19 - 25 kJ/mol which was slightly larger than that in bulk water (18 kJ/mol). This relationship can be considered to be due to both the pore structure development and high activation energy of water (18-23 kJ/mol) in the vicinity of smectite surface (within 2 nm) on the basis of molecular dynamics simulations.
Sekiguchi, Tetsuhiro; Shimoyama, Iwao; Baba, Yuji; Sekiguchi, Hiromi*
KEK Proceedings 2001-13, p.24 - 25, 2001/06
no abstracts in English
Sekiguchi, Tetsuhiro; Sekiguchi, Hiromi*; Imamura, Motoyasu*; Matsubayashi, Nobuyuki*; Shimada, Hiromichi*; Baba, Yuji
Surface Science, 482-485(Part.1), p.279 - 284, 2001/06
no abstracts in English
Suzuki, Satoru; Kawamura, Katsuyuki*
JNC TN8400 2001-005, 41 Pages, 2001/04
A correlation between molecular structure and a vibrational spectrum of interlayer water in Na-smectite was investigated by means of Molecular Dymamics (MDs) simulations. Detailed comparison of simulation results with IR spectroscopic observations for the water-smectite system indicated good agreement. Internal vibrational spectra of water were obtained by the Fourier transformation of velocty auto-correlation function of hydrogen atom. A stretching vibrational spectrum of interlayer water consisted of a broad band with a peak top around 3400cm and a sharp peak around 3650 to 3700cm. The fomer broad band was assigned to O-H vibrations between water molecules as bulk water, while the latter band was attributed to O-H ones oriented to siloxane surface through hydrogen bonding. The hydrogen bond distance, determined as the shortest O-O distance by the radial distribution function (RDF), revealed that hydrogen bond distance between water and siloxane surface (O-O 3.0 -O = ca. 2.8 AA ). These results suggested that interaction between water molecule and siloxane surface weaker than that between water molecules, although they were forced to be oriented.
Sekiguchi, Tetsuhiro; Sekiguchi, Hiromi*; Imamura, Motoyasu*; Matsubayashi, Nobuyuki*; Shimada, Hiromichi*; Baba, Yuji
Photon Factory Activity Report 1999, Part B, P. 325, 2000/11
no abstracts in English
Saito, Tamotsu; Baba, Shinichi; Eto, Motokuni
JAERI-Research 99-070, p.21 - 0, 2000/01
no abstracts in English
Motooka, Takafumi; Kiuchi, Kiyoshi
JAERI-Research 99-039, 14 Pages, 1999/05
no abstracts in English
Tamada, Masao; ; Omichi, Hideki
Thin Solid Films, 293(1-2), p.113 - 116, 1997/00
Times Cited Count:4 Percentile:33.04(Materials Science, Multidisciplinary)no abstracts in English
Tamada, Masao; ; Omichi, Hideki
Thin Solid Films, 292(1-2), p.164 - 168, 1997/00
Times Cited Count:7 Percentile:46.46(Materials Science, Multidisciplinary)no abstracts in English
Tamada, Masao; ; Hosoi, Fumio; Suwa, Takeshi
BEAMS 1996: Dai-7-Kai Ryushisen No Sentanteki Oyo Gijutsu Ni Kansuru Shimpojiumu, 0, p.157 - 160, 1996/00
no abstracts in English
Tamada, Masao; Omichi, Hideki; *
Thin Solid Films, 274, p.66 - 69, 1996/00
Times Cited Count:4 Percentile:29.13(Materials Science, Multidisciplinary)no abstracts in English
*
Australian Journal of Physics, 48, p.187 - 205, 1995/00
no abstracts in English
Omichi, Hideki
Nuclear Instruments and Methods in Physics Research B, 105, p.302 - 307, 1995/00
Times Cited Count:18 Percentile:83.3(Instruments & Instrumentation)no abstracts in English
Tamada, Masao; Asano, Masaharu; Yoshida, Masaru; Kumakura, Minoru*
Polymer, 32(11), p.2064 - 2069, 1991/00
Times Cited Count:12 Percentile:55.25(Polymer Science)no abstracts in English
Morii, Yukio; Funahashi, Satoru; Ozawa, Kunio*; *; *; *; *
Japanese Journal of Applied Physics, 28(4), p.L618 - L620, 1989/04
Times Cited Count:2 Percentile:17.23(Physics, Applied)no abstracts in English
; ;
Ika Kikaigaku, 56(7), p.313 - 316, 1986/00
no abstracts in English